itunes ipod sync problems

Synchronization problems? (from the iTunes library to iPod)?
My old laptop stopped working so now I'm using my sister. I signed into my iTunes and brought me to a whole new library, no songs. I had about 300, so there is no way for the buy-back plan of all. I updated my iTunes to "iTunes 8" and bought a song and this song is in my library. I connected my iPod to the laptop and clicks "Sync" and appeared a window saying "Are you sure you want to do this, take all the songs from your iPod and replace it with this" or something. I have no idea what to do. I do not really care if my old songs are in my library, I just want to buy songs from now be synchronized to my iPod without deleting the ones I already have on my iPod. (If that makes sense) Sorry this is so long, I do not know how else to explain it. Thanks a bunch!:)
This should give the option to transfer all purchased songs on your iPod. If not just use a computer to iPod ripping program. If you have a Mac, I recommend use Senuti, if you try PC iDump: iDump – Senuti http://www.softpedia.com/get/IPOD-TOOLS/Multimedia-IPOD-tools/iDump.shtml-http://fadingred.org/senuti/
iphone – ipod Application Syncing – Restrictions (FIX)
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